According to http://wowd.org/items/9491.html, the gloves drop from the following mobs at the rate shown

1. Thermaplugg (a boss) .049
2. Grubbis (a boss) .044
3. Irradiated Horror .03
4. Crowd Pummeler 9-60 (a boss).026
5. Arcane Nullifier x-21 .021
6. Dark iron Agent .02
7. Mechanico-Frostwalker .018
8. Mechanized Guardian .012
9. Mechanico-Flamewalker .012
10.Electrocutioner 6000 (a boss).008
11. Peacekeeper Security Suit .008
12. Mechanized Sentry .006
13 Leprous Defender .005

It is curious that the Irradiated Horrors drop the gloves, but the boss associated with them--Vicious Fallout--does not; nor does the Dark Iron Ambassador. Someone reported that the gloves have fallen off of Holdout Medics or Holdout Warriors--but checking Thotbot, the gloves aren't listed as a drop for these guys. Don't know what's going on with that but I sure wouldn't focus on them